This course will examine the chemical and physical properties of f-block elements and their compounds, with an emphasis on the relationship between properties and underlying electronic structure. The concepts of molecular magnetism are introduced and their importance in transition metal and f-element chemistry.

18 hours of lectures and 2 hours of tutorials to be arranged

None

None

90 minute written examination

To provide students with critical insight and understanding of the chemistry and properties of f-elements and their compounds with emphasis on their electronic structure and magnetic properties.

By the end of this course students will be able to:

1. Recall of the names, symbol and position in the periodic table of f-block elements; describe the shape and extent of 4f and 5f orbitals.

2. Describe trends in redox chemistry in the f-block elements, and uses of lanthanides and actinides in the nuclear industry and medicine.

3. Summarise the magnetic properties of transition metal single-ions and explain the differences and similarities between the chemistry of the lanthanides, the actinides and the d-block transition metal elements.

4. Explain magnetic properties based upon molecular structure and predict such properties in molecular systems.

Students must submit at least 75% by weight of the components (including examinations) of the course's summative assessment.